For example, knowing how to tie a Prussik/Autoblock on command is critical, and knowing how to spot an anchor on shore quickly is also awesome. These turn out quicker rescues.
I am also a huge promoter of the Munter Hitch (aka a belay/rappel device made with 1 locking carabiner). This knowledge has proven to be more useful than the pin kit itself.
http://www.whitewaterfreestyle.com/carabiners-safety-gear-whitewater-kayaking/
-Adam Johnson


